My 125 did something like what your describing, wouldnt turn over at all, wouldnt bump start, nothing. Pulled the stator cover off, turned the flywheel backwards by hand, and it freed up. Started fine and ran for over 50 hours before the piston shat itself, so considering the gap of time between it locking up and the piston failing, I would say they were unrelated other than the fact that it was the same bike.
Oh and I pulled the barrel off after I got home and the piston and ring were fine.
If you have pulled he head off and the top of the piston looks fine, myself personally, I would pull the barrel and look for any marks on the cylinder wall, and on side of the piston, if it got hot any seized temporarily then there will be evidence of it on the piston.
Also, if you wanted to be extra safe you could pull the primary cover off to inspect the clutch and kickstart mechanism.