the biggest
simple porting performance increases are:
match reed to case
match cylinder transfer ports to case
radius edge transfer split in cylinder
polish exhaust port/match exhaust flange
clean up flash on cases in transfers, reed etc.
don't forget to size gaskets for new hole sizes
you won't change the powerband unless you change port area/location on the cylinder. as long as port timing stays the same, powerband will stay the same. you just get more flow. if you increase flow, it might feel like you've narrowed the powerband slightly, because you're zinging through the revs quicker... be reasonable though, you're not taking a bunch of material off, just minor cleanups. the transfer split 'edge' is pretty square to start with, so you will narrow the split pretty dramatically (maybe 1mm) to make it radiused (kinda like knife edge, but don't make it sharp, just make it so mix will flow smooth, instead of square-edged like it is stock)
here's a pic of a radius'd transfer split. i have pics of the last one i did, i just can't find them now.
here's a another pic of a radiused transfer. this is wider than ours is stock..
none of these will increase performance like proper squish will though...